 | jimp@specsol-spam-sux.com wrote: \ > In sci.physics Edward Green wrote: > > jimp@specsol-spam-sux.com wrote: > > > > The more I thought about it, the more problems I came up with. > > > <...> > > > The more I think about it, the more I become convinced that the claim > > "solar irradiance increases evaporation rate under otherwise fixed > > conditions" is true, but not because of photoejection of individual > > molecules. It's true because solar irradiance of the liquid surface > > will preferentially deposit energy near the surface, raising the > > temperature of same relative to a fixed nominal system temperature. > > You don't get grant funding for statements like "when the sun is bright, > it is hotter and water evaporates faster when it is warm".
Well, I hope my analysis is at least a _little_ more sophisticated than that. I was suggesting that for not spectacularly unreasonable operational definitions of "hotter", one might observe that an irradiated open system had a higher evaporation rate than a similar unirradiated open system, even when both were nominally the same temperature. One would be overreaching however in requiring some special quantum mechanism for this though: it's comprehensible in terms of where energy is being injected into the systems.
Your copper plate experiment was elegant, BTW, but it exceeds the capabilities of my junk-around-the-house lab. ;-)
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